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Any extra food a plant makes through photosynthesis is stored in its tissue as starch. Testing a leaf for starch is one way to test whether it has been performing photosynthesis. (Adult supervision required.)
The hot water kills the leaf and the alcohol breaks down the chlorophyll, taking the green color out of the leaf. When you put iodine on the leaves, one of them will turn blue-black and the other will be a reddish-brown. Iodine is an indicator that turns blue-black in the presence of starch. The leaf that was in the light turns blue-black, which demonstrates that the leaf has been performing photosynthesis and producing starch.
Try the test again with a variegated leaf (one with both green and white) that has been in the sunlight. A leaf needs chlorophyll to perform photosynthesis — based on that information, where on the variegated leaf do you think you would find starch?